Archivio Istituzionale della RicercaThe structure, thermal stability, and reducibility in H2 of sulfate species formed in MgO-promoted perovskites, LaMn0.5Mg0.5O3·17 MgO, have been studied by infrared spectroscopy, temperature-programmed desorption, and temperature-programmed reduction−mass spectrometry. Sulfation at 1073 K generates on the MgO phase both bulk and subsurface sulfates, whereas the latter species are the major product of sulfation at room temperature. In contrast with high-surface MgO samples (where sulfate species of covalent nature are found), the surface species closely resemble those in the bulk. Bulk sulfates are more resistant to thermal treatments than surface sulfates. A transformation of bulk sulfates at higher temperature into sulfides is suggested by IR spectroscopy and proved by chemical analysis. SO2, SO, and H2S are the products of sulfate reduction.
Sulfate species in MgO-supported LaMn0.5Mg0.5O3 perovskites: an insigh into the chemistry of MgO / I., Rosso; Fiorilli, SONIA LUCIA; Onida, Barbara; Saracco, Guido; Garrone, Edoardo. - In: JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL. - ISSN 1520-6106. - 106:46(2002), pp. 11980-11984. [10.1021/jp0257808]
Sulfate species in MgO-supported LaMn0.5Mg0.5O3 perovskites: an insigh into the chemistry of MgO
FIORILLI, SONIA LUCIA;ONIDA, BARBARA;SARACCO, GUIDO;GARRONE, EDOARDO
2002
Abstract
The structure, thermal stability, and reducibility in H2 of sulfate species formed in MgO-promoted perovskites, LaMn0.5Mg0.5O3·17 MgO, have been studied by infrared spectroscopy, temperature-programmed desorption, and temperature-programmed reduction−mass spectrometry. Sulfation at 1073 K generates on the MgO phase both bulk and subsurface sulfates, whereas the latter species are the major product of sulfation at room temperature. In contrast with high-surface MgO samples (where sulfate species of covalent nature are found), the surface species closely resemble those in the bulk. Bulk sulfates are more resistant to thermal treatments than surface sulfates. A transformation of bulk sulfates at higher temperature into sulfides is suggested by IR spectroscopy and proved by chemical analysis. SO2, SO, and H2S are the products of sulfate reduction.
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https://hdl.handle.net/11583/1401249
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