The catalytic properties of CuO supported on ceria or ceria-zirconia mixed oxides have been investigated in the preferential oxidation of CO in H 2-rich gases. CuO/CeO2 shows very high activity towards the oxidation of CO with a light-off temperature of about 70°C. This catalyst is very selective for the oxidation of CO rather than of H2 in the low temperature region (70-120°C), while at higher temperatures, the oxidation of hydrogen begins, causing of a maximum of CO conversion to arise with increasing temperature
SUPPORTED CuO/Ce1-xZrxO2 CATALYSTS FOR THE PREFERENTIAL OXIDATION OF CO IN H2-RICH GASES / Caputo, T.; Pirone, Raffaele; Russo, G.. - In: KINETICS AND CATALYSIS. - ISSN 0023-1584. - STAMPA. - 47:5(2006), pp. 756-764. [10.1134/S0023158406050156]
SUPPORTED CuO/Ce1-xZrxO2 CATALYSTS FOR THE PREFERENTIAL OXIDATION OF CO IN H2-RICH GASES
PIRONE, RAFFAELE;
2006
Abstract
The catalytic properties of CuO supported on ceria or ceria-zirconia mixed oxides have been investigated in the preferential oxidation of CO in H 2-rich gases. CuO/CeO2 shows very high activity towards the oxidation of CO with a light-off temperature of about 70°C. This catalyst is very selective for the oxidation of CO rather than of H2 in the low temperature region (70-120°C), while at higher temperatures, the oxidation of hydrogen begins, causing of a maximum of CO conversion to arise with increasing temperaturePubblicazioni consigliate
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https://hdl.handle.net/11583/2496671
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