Three controlled/living polymerization processes, namely atom transfer radical polymerization (ATRP), ring opening polymerization (ROP) and iniferter polymerization, and photoinduced radical coupling reaction were combined for the preparation of ABCBD-type H-shaped complex copolymer. First, a-benzophenone functional polystyrene (BP-PS) and poly( methyl methacrylate) (BP-PMMA) were prepared independently by ATRP. The resulting polymers were irradiated to form ketyl radicals by hydrogen abstraction of the excited benzophenone moieties present at each chain end. Coupling of these radicals resulted in the formation of polystyrene-b-poly(methyl methacrylate) (PS-b-PMMA) with benzpinacole structure at the junction point possessing both hydroxyl and iniferter functionalities. ROP of e-caprolactone (CL) by using PS-b-PMMA as bifunctional initiator, in the presence of stannous octoate yielded the corresponding tetrablock copolymer, PCL-PSPMMA- PCL. Finally, the polymerization of tert-butyl acrylate (tBA) via iniferter process gave the targeted H-shaped block copolymer.

Synthesis of H-Shaped Complex Macromolecular Structures by Combination of Atom Transfer Radical Polymerization, Photoinduced Radical Coupling, Ring-Opening Polymerization, and Iniferter Processes / Aydogan Temel, B.; Amici, JULIA GINETTE NICOLE; Sangermano, Marco; Yagci, Y.. - In: JOURNAL OF POLYMER SCIENCE. PART A, POLYMER CHEMISTRY. - ISSN 1099-0518. - STAMPA. - 51:(2013), pp. 4601-4607. [10.1002/pola.26879]

Synthesis of H-Shaped Complex Macromolecular Structures by Combination of Atom Transfer Radical Polymerization, Photoinduced Radical Coupling, Ring-Opening Polymerization, and Iniferter Processes

AMICI, JULIA GINETTE NICOLE;SANGERMANO, MARCO;
2013

Abstract

Three controlled/living polymerization processes, namely atom transfer radical polymerization (ATRP), ring opening polymerization (ROP) and iniferter polymerization, and photoinduced radical coupling reaction were combined for the preparation of ABCBD-type H-shaped complex copolymer. First, a-benzophenone functional polystyrene (BP-PS) and poly( methyl methacrylate) (BP-PMMA) were prepared independently by ATRP. The resulting polymers were irradiated to form ketyl radicals by hydrogen abstraction of the excited benzophenone moieties present at each chain end. Coupling of these radicals resulted in the formation of polystyrene-b-poly(methyl methacrylate) (PS-b-PMMA) with benzpinacole structure at the junction point possessing both hydroxyl and iniferter functionalities. ROP of e-caprolactone (CL) by using PS-b-PMMA as bifunctional initiator, in the presence of stannous octoate yielded the corresponding tetrablock copolymer, PCL-PSPMMA- PCL. Finally, the polymerization of tert-butyl acrylate (tBA) via iniferter process gave the targeted H-shaped block copolymer.
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11583/2518486
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo