Archivio Istituzionale della RicercaRecently, Sawada [Phys. Rev. E 88, 032406 (2013)] proposed a model to take into account the dielectric dispersion of ionic origin in a weak electrolyte cell. We first show that the model is based on questionable assumptions. Next, we point out an error in the author's calculation of the current in the external circuit. Finally, we demonstrate why some criticism on recent papers is irrelevant.
Comment on “Modeling of electrode polarization for electrolytic cells with a limited ionic adsorption” / A. L., Alexe Ionescu; Barbero, Giovanni; I., Lelidis. - In: PHYSICAL REVIEW E, STATISTICAL, NONLINEAR, AND SOFT MATTER PHYSICS. - ISSN 1539-3755. - 89:(2014). [10.1103/PhysRevE.89.056401]
Comment on “Modeling of electrode polarization for electrolytic cells with a limited ionic adsorption”
BARBERO, GIOVANNI;
2014
Abstract
Recently, Sawada [Phys. Rev. E 88, 032406 (2013)] proposed a model to take into account the dielectric dispersion of ionic origin in a weak electrolyte cell. We first show that the model is based on questionable assumptions. Next, we point out an error in the author's calculation of the current in the external circuit. Finally, we demonstrate why some criticism on recent papers is irrelevant.
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https://hdl.handle.net/11583/2588767
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